By Darrel Dunn, Ph.D., PG, Consulting Hydrogeologist
The purpose of this web page is to present my comments on groundwater topics addressed in emails from viewers of this site. These comments are brief statements related to questions and comments in the viewer's emails. They are not comprehensive coverage of the topic.
Gas in Groundwater
Methane and hydrogen sulfide are common dissolved gasses in groundwater. Methane can produce an explosive atmosphere if concentrated in an enclosed space in a house or other enclosure. The web pages on this site titled Subsurface Methane West US and Subsurface Methane New Mexico contain much information on the occurrence of methane in groundwater.
Low concentrations of hydrogen sulfide may impart an unpleasant odor often described as a "rotten egg" smell. Hydrogen sulfide may be produced by reduction of sulfate in groundwater that has a low oxygen concentration. Such chemical reduction may be augmented by the action of anaerobic bacteria if organic material is present. Hydrogen sulfide in the low concentrations associated with the foul odor may cause health effects. An OSHA Fact Sheet says that "repeated or prolonged exposures may cause eye inflammation, headache, fatigue, irritability, insomnia, digestive disturbances and weight loss." A CDC Fact Sheet says that hydrogen sulfide has not been shown to cause cancer in humans. This fact sheet also states that the EPA has determined that data for hydrogen sulfide are inadequate for carcinogenic assessments. Hydrogen sulfide is corrosive to metals, can cause yellow or black stains on kitchen and bathroom fixtures, and can discolor and affect taste of beverages and cooked foods.
Two ways to deal with gas in water from a well are (1) explore for productive layers in the aquifer that do not contain gas, and (2) remove the gas from the water produced by the existing well. One way to remove water is by aeration. There are various ways to aerate the water. Some are installed within the well, others treat the produced water.
Acrylamide in Groundwater
Operations that clean or process sand from sand mines commonly use polyacrylamide (PAM) as a flocculant to remove unwanted minerals and fines from water used to wash the sand. Acrylamide (AMD) is a chemical used in the production of polyacrylamide. Therefore, residual acrylamide may be present in industrial sand wash water, wastewater, and sludges. Acrylamide is water soluble and unlikely to adsorb to organic and inorganic soil components. Consequently, potential for groundwater contamination may be a risk associated with the use of PAM as a flocculant. Polyacrylamide itself is generally considered not toxic, but acrylamide is considered by the United States EPA to be a likely human carcinogen and neurotoxin.
Groundwater Age Dating
The age of groundwater ranges from less than a month to more than a million years. The following image shows some of the methods for dating the age of groundwater and the age for which each method is applicable.
Argon (Ar) is a dissolved gas, so sample collection without dissolution of the gas involves special equipment used with great care. The helium (He) method also requires dealing with a dissolved gas, plus the interpretation of the laboratory results is complicated. Sample collection for Carbon-14 is about as easy as filling a bottle. However, analysis of laboratory results is complicated by chemical reaction between carbon in the groundwater and carbon in such rocks as limestone. Post-processing of laboratory results to adjust for the carbon reactions increases uncertainty.
Interpretation of laboratory results for groundwater age is very complex. One problem is that almost all groundwater samples are mixtures of water of varying age, combining all of the flowlines reaching a well or spring. Another problem is that the groundwater may contain a very small proportion of connate water diffused from clay or other low permeable material. If the connate water is extremely old even a very low admixture can cause the water to appear to be much older than it really is. There are many other problems.
Another way to estimate the age of groundwater is to develop a computer model of the system and use particle tracking. It might be useful to compare particle tracking results to the results of dating the age of a water sample.
Coastal Saltwater Intrusion
Real groundwater systems affected by saltwater intrusion are dynamic and the Ghyben-Hertzberg relation, being based on a static system, does not strictly apply. Both the saltwater and the fresh water are moving and the movement changes with time. The systems have a history, and at any given time you are just seeing the state of the system at that time. Ghyben-Hertzberg helps one understand the saltwater-freshwater relationship, but the principles of geology, chemistry and physics determine it. If the characterization of the system is over-simplified, it may be wrong. More information on saltwater intrusion may be viewed on the web page titled Saltwater Intrusion.